Experimental study of CH4 catalytic combustion on various catalysts
Abstract
The objective of this paper is to study the reaction performance of methane catalytic combustion on different catalyst and the hydrogen assisted combustion in a monolith honeycomb reactor experimentally. The characteristics of catalytic ignition and reaction with different promoters are investigated for the development of more efficient technology and improvement of precious metal catalyst. This paper presents experimental results on CH4 and H2 assisted catalytic combustion performance of four cordierite-based honeycomb catalyst. The experimental results show that the catalyst with different promoters show different reaction activities, the needed combustor inlet temperature can be lower as the catalyst temperature can be increased by the heat release due to catalytic hydrogen oxidation at lower temperature, the hydrogen addition ensures light-off of ultra low heat value fuel.References
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[17]SHIM K S, HILAIRE L, NORMAND F L, et al. Catalysis by palladium-rare-earth-metal(REPd) intermetallic compounds: hydrogenation of but-1-ene, buta-1, 3-diene and but-1-yne[J]. Chem Soc Faraday Trans, 1991,87(9):1453-1460.
[2] Su S, Beath AC, Mallett CW. A method and system for combustion of methane. Australian patent No. 2,002,951,703; 2002.
[3] E. Magnus Johansson, K.M. Jonny Danielsson, Catalytic combustion of gasified biomass over hexaaluminate catalysts: influence of palladium loading and ageing, Applied catalysis A: General , 182(1999) 199-208.
[4] Cimino S, Pirone R, Russo G, Thermal stability of perpvskite-based monolithic reactors in the catalytic combustion of methane, Ind Eng Chem Res, 40(2001)80–5.
[5] Heck RM, Gulati S, Farrauto RJ, The application of monoliths for gas phase catalytic reactions, Chem Eng J, 82 (2001)149–56.
[6] Marin P, Hevia MAG, Ordonez S, Diez F, Combustion of methane lean mixtures in reverse flow reactors: comparison between packed and structured catalyst beds, Catal Today, 105(2005)701–8.
[7] Lee JH, Trimm DL, Catalytic combustion of methane, Fuel Process Technol, 42(1995)339–59.
[8] Ledwich J, Bhatia S, Su S. Catalytic combustion of coal mine ventilation air: literature review and experimental preparation, CSIRO Exploration and Mining, May 2001.
[9] Sławomir Morel ， The afterburning of carbon monoxide in natural gas combustion gases in the presence of catalytic ceramic coatings， Journal of Power Technologies 92 (2) (2012) 109–114
[10]Xiao Li-hua,Yang Yu-xia,Sun Kun-peng, Study of CH4 low temperature catalytic combustion on Pd/CeO2 catalyst-effect of preparations on catalyst performance, Petrochemical, 15(2004)192-193.
[11]Gao Li-ping,Liu Jian-zhou,Wu Jie, Characterization of reactivity and activation energy for catalytic combustion of methane on Pd-M/ Al2O3, Journal of China University of Mining & Technology, 39(2010)859-864.
[12]YeiChin Chao, GuanBang Chen, HungWei Hsu, Catalytic combustion of gasified biomass in a platinum monolith honeycomb reactor, Applied Catalysis A: General, (1) 261(2004)99-107.
[13]Shi su, Jenny Agnew. Catalytic combustion of coal mine ventilation air methane,Fuel,(6)85 (2006)1201-1210.
[14]Deutschmann, L. I. Maie, U. Riedel, A. H. Stroemman and R. W. Dibble. Hydrogen assisted catalytic combustion of methane on platinum[J]. Catalysis Today, 2000, 59(1-2): 141-150.
[15]P. Mériaudeau, O. H. Ellestad, M. Dufaux and C. Naccache et al．Metal-support interaction. Catalytic properties of TiO2-supported platinum, iridium and rhodium[J]. Journal of catalysis, 1982,75(2): 243-250.
[16]S.J.Tauster, S.C.Fung, R.L.Garten. Strong metal-support interactions. Group 8 noble metals supported on titanium dioxide[J]. Journal of American Chemistry society 1978, 100(1): 170-175.
[17]SHIM K S, HILAIRE L, NORMAND F L, et al. Catalysis by palladium-rare-earth-metal(REPd) intermetallic compounds: hydrogenation of but-1-ene, buta-1, 3-diene and but-1-yne[J]. Chem Soc Faraday Trans, 1991,87(9):1453-1460.
Published
2013-08-09
How to Cite
LIU, Aiguo et al.
Experimental study of CH4 catalytic combustion on various catalysts.
Journal of Power Technologies, [S.l.], v. 93, n. 3, p. 142--148, aug. 2013.
ISSN 2083-4195.
Available at: <https://papers.itc.pw.edu.pl/index.php/JPT/article/view/418>. Date accessed: 22 dec. 2024.
Issue
Section
Combustion and Fuel Processing
Keywords
Catalytic combustion; Cordierite-based honeycomb catalyst; Catalytic ignition
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